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------=_NextPart_01C68C9B.E325E990 Content-Location: file:///C:/E327C959/PolymerNanoclayMixingTechnology_files/pres.xml Content-Transfer-Encoding: quoted-printable Content-Type: text/xml; charset="utf-8" ------=_NextPart_01C68C9B.E325E990 Content-Location: file:///C:/E327C959/PolymerNanoclayMixingTechnology_files/slide0001.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Polymer/Nanoclay Mixing Technology
Polymer/Nanoclay = Mixing Technology
Carl D. McAfee, Ph.D.
17 March 2006
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Overview of Presentation
nRubber, Plastics, and new mixing equipment
nRubber – two roll mill, banbury, intermeshing
nPlastics – twin screw extruder
nEvaluation of polymer/nanoclay materials
nDetermination of degree of exfoliation
nAnalytical methods – XRD, TEM, rheological
nPolymer/Nanoclay masterbatches
nPolymers to date – NBR, HNBR, EVA, EPDM
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The Mixing Challenge
nIn a rubber matrix
nHow do we exfoliate the clay platelets in the polymer matrix without destroying the elastic polymer component?
nTraditional rubber mixing equipment
nMixes the polymer but does not exfoliate clay
nPlastics mixing equipment
nExfoliates nanoclay but breaks the polymer
nProprietary mixing process
nNew technology appears to be successful
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Evaluation of Polymer/Clay
nInitial method for determining exfoliation
nXRD – xray diffraction methods – d-spacing&#= 13;
nThis works nice in plastics at low levels of clay
nMethod falls short in rubber at higher levels
nTEM method added to obtain visual images
nWe can see nice images & degree of exfoliation <= /span>
nMethod is costly, time consuming & difficult
nRheological methods are being successful
nGiving indirect measurements of exfoliation
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Polymer/Nanoclay Masterbatches
nThe following sli= des illustrate mixing & exfoliation with proprietary mixing technology nThe polymer system evaluated most extensively are the NBR & HNBR systems nOther polymer sys= tems mixed showing similar results are EPDM & EVA = nUltima= tely final compounds, physical properties, and performance in end u= se applications will determine acceptance
------=_NextPart_01C68C9B.E325E990 Content-Location: file:///C:/E327C959/PolymerNanoclayMixingTechnology_files/slide0008.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Polymer/Nanoclay Mixing Technology
XRD – NBR-20 Rubber Mixing
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XRD – MC-DOE 1-5 - Worst
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XRD – Twin Screw
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